Title : Biodiesel feed stock potential and biochemical properties of defatted seeds of some tropical wild oleaginous plants
Abstract:
A sustainable biodiesel program must take into consideration food security issues. A study was carried out to estimate the biodiesel feedstock potential of four tropical oleaginous seeds. The bio availability of nutrients and toxicity of their defatted seeds were also investigated. The seeds selected were Ricinodendron heudelotii (njangsa), Cucurbita maxima (pumpkin), Citrullus lanatus (watermelon) and Raphia hookeri (raphia). Oil was extracted from the seeds using a manual hydraulic press at 200 bars and filtered using a filter paper of 400microns. About 100g of each oil sample was subjected to transesterification reaction with methanol (99.98% pure) in a proportion of 6:1 in the presence of sodium hydroxide as a catalyst (1g) for 1 hour, mixing at a rate of 500rpm, and at temperature between 60 and 65 °C. Nutrient availability and toxicity of the defatted cakes were investigated using weanling Wistar albino laboratory rats aged 21 – 23 days old. All four oil samples had high conversion rates to biodiesel ranging from 79 % to 96.5 %. Infrared spectroscopy (FT-IR) of both the straight vegetable oils and produced biodiesel confirmed the conversion of triglycerides into methyl esters. The biodiesel quality parameters of the four methyl esters were: density (790.85 to 823.11 kg/m3), kinematic viscosity (0.88 to 2.03 Pa.S), saponification value (182.4 to 210.4 mgKOH/g), sulphur content (1054.0 to 1840.1 ppm) calorific value (40.5 to 41.4 MJ/Kg), cetane number (65.5 to 68) and flash point (188.5 to 192.7 oC). In vivo studies showed a general decrease in growth performance and haematological indices of the test groups (D1, D2, and D3) when compared to the standard (D4). No mortality was registered amongst the wistar rats fed with the test diets. The biodiesel results showed that all four oils have the potential to be used as alternative cheap feedstock for biodiesel production. The results from the defatted seeds showed no toxicity in the defatted cakes meaning that they can be used for human and animal nutrition.